Search results for " tellurite"
showing 5 items of 5 documents
Ochrobactrum sp. MPV1 from a dump of roasted pyrites can be exploited as bacterial catalyst for the biogenesis of selenium and tellurium nanoparticles
2017
Bacteria have developed different mechanisms for the transformation of metalloid oxyanions to non-toxic chemical forms. A number of bacterial isolates so far obtained in axenic culture has shown the ability to bioreduce selenite and tellurite to the elemental state in different conditions along with the formation of nanoparticles—both inside and outside the cells—characterized by a variety of morphological features. This reductive process can be considered of major importance for two reasons: firstly, toxic and soluble (i.e. bioavailable) compounds such as selenite and tellurite are converted to a less toxic chemical forms (i.e. zero valent state); secondly, chalcogen nanoparticles have att…
Assembly, growth and conductive properties of tellurium nanorods produced by Rhodococcus aetherivorans BCP1
2018
AbstractTellurite (TeO32−) is a hazardous and toxic oxyanion for living organisms. However, several microorganisms can bioconvert TeO32− into the less toxic form of elemental tellurium (Te0). Here, Rhodococcus aetherivorans BCP1 resting (non-growing) cells showed the proficiency to produce tellurium-based nanoparticles (NPs) and nanorods (NRs) through the bioconversion of TeO32−, depending on the oxyanion initial concentration and time of cellular incubation. Te-nanostructures initially appeared in the cytoplasm of BCP1 cells as spherical NPs, which, as the exposure time increased, were converted into NRs. This observation suggested the existence of an intracellular mechanism of TeNRs assem…
Tellurites fibers for infrared supercontinuum sources : opto-geometric profiles and extrinsic absorptions management
2016
This PhD thesis work focuses on the synthesis and purification of vitreous materials used for the development of waveguides with varied profiles, dedicated to supercontinuum (SC) generation between 1 and 5 μm.Concerning the purification of tellurite glasses, several leads were followed, but best results are obtained for the purification of the TeO2-ZnO-Na2O glassy system by the means of zinc fluoride. Attenuation measurements performed on several meter-long single-index fiber samples reveal the nearly complete elimination of water-related absorptions between 3 and 4 μm (OH ions concentration lower than 1 ppm mass.). Such water-purified glasses were firstly dedicated to microstructured optic…
Fibres optiques à coeur supendu en verre d'oxyde de tellure et génération d'effets non linéaires dans l'infrarouge au-delà de 2 microns
2012
The work reported in this thesis deals with the fabrication of suspended core tellurite microstructured optical fibers (MOFs) for supercontinuum generation beyond 2 µm. In order to reach our aim, we first studied thermal and optical properties of TeO2-ZnO-R2O and TeO2-WO3-R2O (where R = Li, Na and K) glasses. The glass 80TeO2-10ZnO-10Na2O (molar %) has been chosen in order to make MOFs for characterization of the generated non linear optical effects. Synthesis performed under dry and oxidative atmosphere allowed us to reduce the hydroxyl groups concentration by a factor of 30 compared to fabrication in air atmosphere. Use of dehydrating agents (ZnF2 and TeCl4) allowed to reduce again the OH…
Study of supercontinuum sources based on tellurite glass optical fibers for mid-infrared absorption spectroscopy applied to gas sensing
2015
This work focuses on the development of mid-infrared supercontinuum light sources and their application for gas detection through absorption spectroscopy. The study of supercontinuum sources is based on nonlinear ultrashort pulse propagation in tellurite glass (80TeO2-10ZnO-10Na2O) and used in three different forms, namely a thin bulk sample, a microstructured suspended-core fiber, and a tapered suspended-core fiber. These technical means adapt themselves to distinct laser sources commercially available, thus optimizing the implementation of ultrawide-band infrared light sources. Experimental observations are compared to corresponding numerical simulations, thus pointing out the different u…